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Benchmarking lithium amide versus amine bonding by charge density and energy decomposition analysis arguments
Lithium amides are versatile C–H metallation reagents with vast industrial demand because of their high basicity combined with their weak nucleophilicity, and they are applied in kilotons worldwide annually. The nuclearity of lithium amides, however, modifies and steers reactivity, region- and stere...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5916014/ https://ncbi.nlm.nih.gov/pubmed/29732094 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05368a |
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