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Azaadamantyl Nitroxide Spin Label: Complexation with β-Cyclodextrin and Electron Spin Relaxation

An iodoacetamide azaadamantyl spin label was studied in fluid solution and in 9:1 trehalose:sucrose glass. In 9:1 toluene:CH(2)Cl(2) solution at 293 K the isotropic nitrogen hyperfine coupling is 19.2 G, T(1) is 0.37 μs and T(2) is 0.30 to 0.35 μs. Between about 80 and 150 K 1/T(m) in 9:1 trehalose:...

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Dettagli Bibliografici
Pubblicato in:Free Radic Res
Autori principali: Eaton, Sandra S., Rajca, Andrzej, Yang, Zhimin, Eaton, Gareth R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2017
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5908751/
https://ncbi.nlm.nih.gov/pubmed/28946790
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1080/10715762.2017.1384954
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