Electron Spin-Lattice Relaxation Mechanisms of Rapidly-Tumbling Nitroxide Radicals

Electron spin relaxation times at 295 K were measured at frequencies between 250 MHz and 34 GHz for perdeuterated 2,2,6,6-tetramethyl-4-piperidone-1-oxyl (PDT) in five solvents with viscosities that result in tumbling correlation times, τ(R,) between 4 and 50 ps and for three (14)N/(15)N pairs of ni...

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Main Authors: Biller, Joshua R., Elajaili, Hanan, Meyer, Virginia, Rosen, Gerald M., Eaton, Sandra S., Eaton, Gareth R.
Formato: Artigo
Idioma:Inglês
Publicado: 2013
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3952064/
https://ncbi.nlm.nih.gov/pubmed/24056272
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmr.2013.08.006
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