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Electron Spin-Lattice Relaxation Mechanisms of Rapidly-Tumbling Nitroxide Radicals
Electron spin relaxation times at 295 K were measured at frequencies between 250 MHz and 34 GHz for perdeuterated 2,2,6,6-tetramethyl-4-piperidone-1-oxyl (PDT) in five solvents with viscosities that result in tumbling correlation times, τ(R,) between 4 and 50 ps and for three (14)N/(15)N pairs of ni...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3952064/ https://ncbi.nlm.nih.gov/pubmed/24056272 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmr.2013.08.006 |
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