Nalaganje...

The vinylogous Catellani reaction: a combined computational and experimental study

In the presence of 5 mol% Pd(OAc)(2), 1 equiv. of norbornene, and K(2)CO(3), the reaction of 4-iodo-2-quinolones with tertiary o-bromobenzylic alcohols produced the desired benzopyran-fused 2-quinolones in moderate to high yields. A Catellani-type mechanism involving vinylic C–H cleavage is proposed...

Popoln opis

Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Yamamoto, Y., Murayama, T., Jiang, J., Yasui, T., Shibuya, M.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2017
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5885779/
https://ncbi.nlm.nih.gov/pubmed/29675164
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04265e
Oznake: Označite
Brez oznak, prvi označite!