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A combined experimental and computational study on the reaction of fluoroarenes with Mg–Mg, Mg–Zn, Mg–Al and Al–Zn bonds

Through a combined experimental and computational (DFT) approach, the reaction mechanism of the addition of fluoroarenes to Mg–Mg bonds has been determined as a concerted S(N)Ar-like pathway in which one Mg centre acts as a nucleophile and the other an electrophile. The experimentally determined Gib...

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Bibliografiset tiedot
Julkaisussa:Chem Sci
Päätekijät: Bakewell, Clare, Ward, Bryan J., White, Andrew J. P., Crimmin, Mark R.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: Royal Society of Chemistry 2018
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC5897846/
https://ncbi.nlm.nih.gov/pubmed/29719707
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05059c
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