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A combined experimental and computational study on the reaction of fluoroarenes with Mg–Mg, Mg–Zn, Mg–Al and Al–Zn bonds
Through a combined experimental and computational (DFT) approach, the reaction mechanism of the addition of fluoroarenes to Mg–Mg bonds has been determined as a concerted S(N)Ar-like pathway in which one Mg centre acts as a nucleophile and the other an electrophile. The experimentally determined Gib...
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| 發表在: | Chem Sci |
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| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Royal Society of Chemistry
2018
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5897846/ https://ncbi.nlm.nih.gov/pubmed/29719707 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05059c |
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