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The vinylogous Catellani reaction: a combined computational and experimental study
In the presence of 5 mol% Pd(OAc)(2), 1 equiv. of norbornene, and K(2)CO(3), the reaction of 4-iodo-2-quinolones with tertiary o-bromobenzylic alcohols produced the desired benzopyran-fused 2-quinolones in moderate to high yields. A Catellani-type mechanism involving vinylic C–H cleavage is proposed...
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| Udgivet i: | Chem Sci |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5885779/ https://ncbi.nlm.nih.gov/pubmed/29675164 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04265e |
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