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The mechanism of directed Ni(ii)-catalyzed C–H iodination with molecular iodine
The density functional theory method is used to elucidate the elementary steps of Ni(ii)-catalyzed C(sp(2))–H iodination with I(2) and substrates bearing N,N′-bidentate directing centers, amide-oxazoline (AO) and 8-aminoquinoline (AQ). The relative stability of the lowest energy high- and low-spin e...
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| 發表在: | Chem Sci |
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| Main Authors: | , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Royal Society of Chemistry
2017
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5883947/ https://ncbi.nlm.nih.gov/pubmed/29675159 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04604a |
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