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Mono-N-protected amino acid ligands stabilize dimeric palladium(ii) complexes of importance to C–H functionalization

Mono-protected amino acid (MPAA) ligands are used in a number of Pd-catalyzed C–H functionalization reactions. MPAAs have been proposed to bind to Pd(ii) via κ(2)-(N,O) coordination, but such binding has not yet been experimentally validated. Herein, we report the synthesis and detailed characteriza...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Gair, Joseph J., Haines, Brandon E., Filatov, Alexander S., Musaev, Djamaladdin G., Lewis, Jared C.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5859881/
https://ncbi.nlm.nih.gov/pubmed/29619194
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01674c
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