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Can Donor Ligands Make Pd(OAc)(2) a Stronger Oxidant? Access to Elusive Palladium(II) Reduction Potentials and Effects of Ancillary Ligands via Palladium(II)/Hydroquinone Redox Equilibria

Palladium(II)-catalyzed oxidation reactions represent an important class of methods for selective modification and functionalization of organic molecules. This field has benefitted greatly from the discovery of ancillary ligands that expand the scope, reactivity, and selectivity in these reactions;...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Bruns, David L., Musaev, Djamaladdin G., Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7678807/
https://ncbi.nlm.nih.gov/pubmed/33167610
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c09464
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