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Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes

[Image: see text] Gold(I) acetylide and σ,π-digold(I) alkyne complexes derived from one prototypical 1,6-enyne and from 7-ethynyl-1,3,5-cycloheptatriene have been prepared and structurally characterized. Their possible role in gold(I)-catalyzed cycloisomerizations has been studied by experiment and...

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Detalhes bibliográficos
Publicado no:Organometallics
Main Authors: Ferrer, Sofia, Echavarren, Antonio M.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2017
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5850095/
https://ncbi.nlm.nih.gov/pubmed/29551852
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.7b00668
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