Wordt geladen...
σ–π-Diauration as an alternative binding mode for digold intermediates in gold(i) catalysis
While investigating the gold(i)-catalyzed intramolecular hydroarylation of allenes, the structure of a digoldvinyl intermediate was verified. Instead of the previously proposed geminally diaurated binding mode for the digold when L = PPh(3), an alternative σ–π-diauration mode was observed with the b...
Bewaard in:
| Hoofdauteurs: | , |
|---|---|
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2012
|
| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3729438/ https://ncbi.nlm.nih.gov/pubmed/23914295 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC21281A |
| Tags: |
Voeg label toe
Geen labels, Wees de eerste die dit record labelt!
|