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Dinuclear Gold–Silver Resting States May Explain Silver Effects in Gold(I)-Catalysis

[Image: see text] The resting state of the gold(I)-catalyzed hydroarylation of 1 changes in the presence of Ag(+), with silver free catalysts resting at the dinuclear gold structure 5 and Ag(+) containing solutions resting at a heteronuclear species like 6. Adventitious Ag(+) (typically from LAuCl a...

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Detalhes bibliográficos
Main Authors: Weber, Dieter, Gagné, Michel R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2913295/
https://ncbi.nlm.nih.gov/pubmed/19807117
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902116b
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