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σ–π-Diauration as an alternative binding mode for digold intermediates in gold(i) catalysis
While investigating the gold(i)-catalyzed intramolecular hydroarylation of allenes, the structure of a digoldvinyl intermediate was verified. Instead of the previously proposed geminally diaurated binding mode for the digold when L = PPh(3), an alternative σ–π-diauration mode was observed with the b...
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| Auteurs principaux: | , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2012
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3729438/ https://ncbi.nlm.nih.gov/pubmed/23914295 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC21281A |
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