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Borostannylation of Alkynes and Enynes. Scope and Limitations of the Reaction and Utility of the Adducts

[Image: see text] The utility of the bis-metallating reagent 1,3-dimethyl-2-trimethylstannyl-2-bora-1,3-diazacyclopentane (1) has not been fully realized because of the hydrolytic instability of the products derived from catalyzed vicinal syn-additions to alkynes. The isolation of variety of such ad...

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Autors principals: Singidi, Ramakrishna Reddy, RajanBabu, T. V.
Format: Artigo
Idioma:Inglês
Publicat: 2010
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2886519/
https://ncbi.nlm.nih.gov/pubmed/20459076
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100824f
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