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Enhanced vibrational solvatochromism and spectral diffusion by electron rich substituents on small molecule silanes
Fourier transform infrared and two-dimensional IR (2D-IR) spectroscopies were applied to two different silanes in three different solvents. The selected solutes exhibit different degrees of vibrational solvatochromism for the Si–H vibration. Density functional theory calculations confirm that this d...
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| Publicado no: | J Chem Phys |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
AIP Publishing LLC
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5848733/ https://ncbi.nlm.nih.gov/pubmed/28964044 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.5003908 |
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