Synthesis and Properties of Open Fullerenes Encapsulating Ammonia and Methane

We describe the synthesis and characterisation of open fullerene (1) and its reduced form (2) in which CH(4) and NH(3) are encapsulated, respectively. The (1)H NMR resonance of endohedral NH(3) is broadened by scalar coupling to the quadrupolar (14) n nucleus, which relaxes rapidly. This broadening...

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Vydáno v:Chemphyschem
Hlavní autoři: Bloodworth, Sally, Gräsvik, John, Alom, Shamim, Kouřil, Karel, Elliott, Stuart J., Wells, Neil J., Horsewill, Anthony J., Mamone, Salvatore, Jiménez‐Ruiz, Mónica, Rols, Stéphane, Nagel, Urmas, Rõõm, Toomas, Levitt, Malcolm H., Whitby, Richard J.
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2018
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5838534/
https://ncbi.nlm.nih.gov/pubmed/29131544
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cphc.201701212
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