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A Solid‐State Intramolecular Wittig Reaction Enables Efficient Synthesis of Endofullerenes Including Ne@C(60), (3)He@C(60), and HD@C(60)
An open‐cage fullerene incorporating phosphorous ylid and carbonyl group moieties on the rim of the orifice can be filled with gases (H(2), He, Ne) in the solid state, and the cage opening then contracted in situ by raising the temperature to complete an intramolecular Wittig reaction, trapping the...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2021
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8048630/ https://ncbi.nlm.nih.gov/pubmed/33554419 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202100817 |
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