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Synthesis and Properties of Open Fullerenes Encapsulating Ammonia and Methane

We describe the synthesis and characterisation of open fullerene (1) and its reduced form (2) in which CH(4) and NH(3) are encapsulated, respectively. The (1)H NMR resonance of endohedral NH(3) is broadened by scalar coupling to the quadrupolar (14) n nucleus, which relaxes rapidly. This broadening...

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Detalhes bibliográficos
Publicado no:Chemphyschem
Main Authors: Bloodworth, Sally, Gräsvik, John, Alom, Shamim, Kouřil, Karel, Elliott, Stuart J., Wells, Neil J., Horsewill, Anthony J., Mamone, Salvatore, Jiménez‐Ruiz, Mónica, Rols, Stéphane, Nagel, Urmas, Rõõm, Toomas, Levitt, Malcolm H., Whitby, Richard J.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5838534/
https://ncbi.nlm.nih.gov/pubmed/29131544
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cphc.201701212
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