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Reductive Decarboxylative Alkynylation of N-Hydroxyphthalimide Esters with Bromoalkynes
A new method for the synthesis of terminal and internal alkynes from the nickel-catalyzed decarboxylative coupling of N-hydroxyphthalimide esters (NHP esters) and bromoalkynes is presented. This reductive cross-electrophile coupling is the first to use a C(sp)-X electrophile, and appears to proceed...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5836783/ https://ncbi.nlm.nih.gov/pubmed/28782860 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706781 |
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