Decarboxylative Alkynylation

The development of a new decarboxylative cross-coupling protocol that affords terminal and substituted alkynes from various carboxylic acids is described using both nickel- and iron-based catalysts. The use of N-hydroxytetrachlorophthalimide (TCNHPI) esters is crucial to the success of the transform...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Smith, Joel M., Qin, Tian, Merchant, Rohan R., Edwards, Jacob T., Malins, Lara R., Liu, Zhiqing, Che, Guanda, Shen, Zichao, Shaw, Scott A., Eastgate, Martin D., Baran, Phil S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2017
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5792189/
https://ncbi.nlm.nih.gov/pubmed/28636185
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705107
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