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Zn-mediated decarboxylative carbagermatranation of aliphatic N-hydroxyphthalimide esters: evidence for an alkylzinc intermediate

Alkyl nucleophiles synthesized by decarboxylation of the corresponding N-hydroxyphthalimide esters (NHP esters) would inherit the complex structure of natural carboxylic acids and result in useful cross-coupling fragments. Herein, we report the synthesis of alkyl carbagermatranes via Zn-mediated dec...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Jiang, Wei-Tao, Yang, Shuo, Xu, Meng-Yu, Xie, Xiu-Ying, Xiao, Bin
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7439774/
https://ncbi.nlm.nih.gov/pubmed/32874490
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04288a
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