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A Water Dimer Shift Activates a Proton Pumping Pathway in the P(R) → F Transition of ba(3) Cytochrome c Oxidase
Broken-symmetry density functional calculations have been performed on the [Fe(a3)(4+), Cu(B)(2+)] state of the dinuclear center (DNC) for the P(R) → F part of the catalytic cycle of ba(3) cytochrome c oxidase (CcO) from Thermus thermophilus (Tt), using OLYP-D3-BJ functional. The calculations show t...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5825212/ https://ncbi.nlm.nih.gov/pubmed/29308889 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b02461 |
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