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Toward a chemical mechanism of proton pumping by the B-type cytochrome c oxidases: Application of Density Functional Theory to cytochrome ba(3) of Thermus thermophilus
A mechanism for proton pumping by the B-type cytochrome c oxidases is presented in which one proton is pumped in conjunction with the weakly-exergonic, two-electron reduction of Fe-bound O(2) to the Fe-Cu bridging peroxodianion, and three protons are pumped in conjunction with the highly-exergonic,...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2653421/ https://ncbi.nlm.nih.gov/pubmed/18928258 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja803112w |
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