1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

Equipped with excellent hydrocarbon solubility, the lithium hydride surrogate 1‐lithium‐2‐tert‐butyl‐1,2‐dihydropyridine (1tLi) functions as a precatalyst to convert Me(2)NH⋅BH(3) to [NMe(2)BH(2)](2) (89 % conversion) under competitive conditions (2.5 mol %, 60 h, 80 °C, toluene solvent) to that of...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: McLellan, Ross, Kennedy, Alan R., Mulvey, Robert E., Orr, Samantha A., Robertson, Stuart D.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
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Full Papers
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5820744/
https://ncbi.nlm.nih.gov/pubmed/28940713
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201703609
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