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Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

In reactions restricted previously to a ruthenium catalyst, a 1‐lithium‐2‐alkyl‐1,2‐dihydropyridine complex is shown to be a competitive alternative dehydrogenation catalyst for the transformation of diamine boranes into cyclic 1,3,2‐diazaborolidines, which can in turn be smoothly arylated in good y...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: McLellan, Ross, Kennedy, Alan R., Orr, Samantha A., Robertson, Stuart D., Mulvey, Robert E.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5396369/
https://ncbi.nlm.nih.gov/pubmed/28000994
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201610905
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