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Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu(3)C(6)H(2))(2)C(6)H(3)X, where X = I, Li, OH, SH, N(3), or NH(2)
A “double benzyne” reaction between 1,3-dichloro-2-iodobenzene and 2,4,6-t-Bu(3)C(6)H(2)MgBr followed by the addition of iodine led to 2,6-(2,4,6-t-Bu(3)C(6)H(2))(2)C(6)H(3)I (HTBTI) in 65% yield. Lithiation of HTBTI with Li-t-Bu gave Li(Et(2)O)(2)HTBT from which HTBTSH, HTBTN(3), HTBTNH(2), and HTB...
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| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5811262/ https://ncbi.nlm.nih.gov/pubmed/28459588 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b01062 |
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