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Alkylation of Dinitrogen in [(HIPTNCH(2)CH(2))(3)N]Mo Complexes (HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3))
In this paper we explore the ethylation of dinitrogen (employing [Et(3)O][BAr(f)(4)]; Ar(f) = 3,5-(CF(3))(2)C(6)H(3)) in [HIPTN(3)N]Mo (Mo) complexes ([HIPTN(3)N](3-) = [N(CH(2)CH(2)NHIPT)(3)](3-); HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)) with the objective of developing a catalytic cycle for...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2747384/ https://ncbi.nlm.nih.gov/pubmed/19673523 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904535f |
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