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CuH-Catalyzed Asymmetric Reduction of α,β-Unsaturated Carboxylic Acids to β-Chiral Aldehydes

The copper hydride (CuH)-catalyzed enantioselective reduction of α,β-unsaturated carboxylic acids to saturated aldehydes is reported. This protocol provides a new method to access a variety of β-chiral aldehydes in good yields, with high levels of enantioselectivity and broad functional group tolera...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Zhou, Yujing, Bandar, Jeffrey S., Liu, Richard Y., Buchwald, Stephen L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5800953/
https://ncbi.nlm.nih.gov/pubmed/29283578
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b12260
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