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Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

Current understanding of ligand effects in transition metal catalysis is mostly based on the analysis of catalyst-substrate through-bond and through-space interactions, with the latter commonly considered to be repulsive in nature. The dispersion interaction between the ligand and the substrate, a u...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Lu, Gang, Liu, Richard Y., Yang, Yang, Fang, Cheng, Lambrecht, Daniel S., Buchwald, Stephen L., Liu, Peng
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5798229/
https://ncbi.nlm.nih.gov/pubmed/29064694
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07373
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