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Synthesis and Characterization of a Heterometallic Extended Architecture Based on a Manganese(II)-Substituted Sandwich-Type Polyoxotungstate

The reaction of [α-P(2)W(15)O(56)](12−) with Mn(II) and Dy(III) in an aqueous basic solution led to the isolation of an all inorganic heterometallic aggregate Na(10)(OH(2))(42)[{Dy(H(2)O)(6)}(2)Mn(4)P(4)W(30)O(112)(H(2)O)(2)]·17H(2)O (Dy(2)Mn(4)-P(2)W(15)). Single-crystal X-ray diffraction revealed...

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Detalhes bibliográficos
Publicado no:Materials (Basel)
Main Authors: Ibrahim, Masooma, Moreno-Pineda, Eufemio, Bergfeldt, Thomas, Anson, Christopher E., Powell, Annie K.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5793653/
https://ncbi.nlm.nih.gov/pubmed/29342122
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma11010155
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