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Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp(3) C−H Bonds
The use of copper in directed C−H oxidation has been relatively underexplored. In a seminal example, Schönecker showed that copper and O(2) promoted the hydroxylation of steroid-containing ligands. Recently, Baran (J. Am. Chem. Soc. 2015, 137, 13776) improved the reaction conditions to oxidize simil...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5792191/ https://ncbi.nlm.nih.gov/pubmed/28654755 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b01069 |
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