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Aminomethylation/hydrogenolysis as an alternative to direct methylation of metalated isoquinolines – a novel total synthesis of the alkaloid 7-hydroxy-6-methoxy-1-methylisoquinoline

Highly-substituted isoquinolines are important scaffolds in syntheses of natural products and in drug development and hence, effective synthetic approaches are required. Here we present a novel method for the introduction of a methyl group at C1 of isoquinolines. This is exemplified by a new total s...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Melzer, Benedikt C, Felber, Jan G, Bracher, Franz
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5789437/
https://ncbi.nlm.nih.gov/pubmed/29441136
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.8
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