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Direct detection of lysine side chain NH(3)(+) in protein-heparin complexes using NMR spectroscopy

Two NMR observables, N(ζ)H(3)(+) peak in the HISQC spectrum and N(ζ) chemical shift difference between the free and heparin-bound forms, can identify binding-interface lysines in protein-heparin complexes. Unlike backbone chemical shifts, these direct probes are stringent and are less prone to eithe...

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Detalhes bibliográficos
Publicado no:Analyst
Main Authors: Sepuru, Krishna Mohan, Iwahara, Junji, Rajarathnam, Krishna
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5788726/
https://ncbi.nlm.nih.gov/pubmed/29292440
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7an01406f
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