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Nickel/Photoredox-Catalyzed Amidation via Alkylsilicates and Isocyanates

A nickel/photoredox, dual-catalyzed amidation reaction between alkylsilicate reagents and alkyl/aryl isocyanates is reported. In contrast to the previously reported reductive coupling process, this protocol is characterized by mild reaction conditions and the absence of a stoichiometric reductant. A...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Zheng, Shuai, Primer, David N., Molander, Gary A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5784433/
https://ncbi.nlm.nih.gov/pubmed/29375927
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b02795
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