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Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

[Image: see text] The cross-coupling of sp(3)-hybridized organoboron reagents via photoredox/nickel dual catalysis represents a new paradigm of reactivity for engaging alkylmetallic reagents in transition-metal-catalyzed processes. Reported here is an investigation into the mechanistic details of th...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Gutierrez, Osvaldo, Tellis, John C., Primer, David N., Molander, Gary A., Kozlowski, Marisa C.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2015
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4576934/
https://ncbi.nlm.nih.gov/pubmed/25836634
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja513079r
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