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Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates

[Image: see text] Single-electron transmetalation is recognized as an enabling technology for the mild transfer of alkyl groups to transition metal catalysts in cross-coupling reactions. Hypercoordinate silicates represent a new and improved class of radical precursors because of their low oxidation...

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Опубликовано в: :J Am Chem Soc
Главные авторы: Jouffroy, Matthieu, Primer, David N., Molander, Gary A.
Формат: Artigo
Язык:Inglês
Опубликовано: American Chemical Society 2015
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC4854202/
https://ncbi.nlm.nih.gov/pubmed/26704168
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b10963
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