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Jumpstarting the cytochrome P450 catalytic cycle with a hydrated electron
Cytochrome P450cam (CYP101Fe(3+)) regioselectively hydroxylates camphor. Possible hydroxylating intermediates in the catalytic cycle of this well-characterized enzyme have been proposed on the basis of experiments carried out at very low temperatures and shunt reactions, but their presence has not y...
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| Publicado no: | J Biol Chem |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Society for Biochemistry and Molecular Biology
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5766938/ https://ncbi.nlm.nih.gov/pubmed/29109145 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M117.813683 |
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