Sulfonylative and Azidosulfonylative Cyclizations by Visible‐Light‐Photosensitization of Sulfonyl Azides in THF

The generation of sulfonyl radicals from sulfonyl azides using visible light and a photoactive iridium complex in THF is described. This process was used to promote sulfonylative and azidosulfonylative cyclizations of enynes to give several classes of highly functionalized heterocycles. The use of T...

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Publicat a:Chemistry
Autors principals: Zhu, Shaoqun, Pathigoolla, Atchutarao, Lowe, Grace, Walsh, Darren A., Cooper, Mick, Lewis, William, Lam, Hon Wai
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5765429/
https://ncbi.nlm.nih.gov/pubmed/28945301
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201704380
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