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Cyclization cascade of allenyl azides: A dual mechanism

A density functional theory based computational approach to describing the mechanistic course of the allene azide cycloaddition cascade sequence has been developed. The results of these calculations permit characterization of key reactive intermediates (diradicals and/or indolidenes), and explain th...

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Detalhes bibliográficos
Main Authors: López, Carlos Silva, Faza, Olalla Nieto, Feldman, Ken S., Iyer, Malliga R., Hester, D. Keith
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2527537/
https://ncbi.nlm.nih.gov/pubmed/17530848
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja070818l
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