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Allenyl Azide Cycloaddition Chemistry. Photochemical Initiation and CuI Mediation Leads to Improved Regioselectivity
[Image: see text] Irradiation of 2-(3-alkenyl)allenylphenyl azides in the presence of excess CuI furnished functionalized 2,3-cyclopentenylindoles in good yield with only trace amounts of competitive C–N-bonded regioisomeric products. These results represent a significant departure from the modest-t...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2788436/ https://ncbi.nlm.nih.gov/pubmed/18345683 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol800429j |
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