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Cyclization cascade of allenyl azides: A dual mechanism
A density functional theory based computational approach to describing the mechanistic course of the allene azide cycloaddition cascade sequence has been developed. The results of these calculations permit characterization of key reactive intermediates (diradicals and/or indolidenes), and explain th...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2007
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2527537/ https://ncbi.nlm.nih.gov/pubmed/17530848 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja070818l |
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