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A facile N-mercaptoethoxyglycinamide (MEGA) linker approach to peptide thioesterification and cyclization

The C-terminal selective electrophilic activation of polypeptides is essential for site-specific peptide modification and conjugation techniques such as Native Chemical Ligation (NCL). Peptide C-terminal α-thioesters are particularly valuable precursors for NCL, due to their hydrolytic stability in...

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Foilsithe in:J Am Chem Soc
Main Authors: Shelton, Patrick M. M., Weller, Caroline E., Chatterjee, Champak
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2017
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5731643/
https://ncbi.nlm.nih.gov/pubmed/28230996
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b13271
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