טוען...
Enhanced Rigidification within a Double Mutant of Soybean Lipoxygenase Provides Experimental Support for Vibronically Nonadiabatic Proton-Coupled Electron Transfer Models
[Image: see text] Soybean lipoxygenase (SLO) is a prototype for nonadiabatic hydrogen tunneling reactions and, as such, has served as the subject of numerous theoretical studies. In this work, we report a nearly temperature-independent kinetic isotope effect (KIE) with an average KIE value of 661 ±...
שמור ב:
| הוצא לאור ב: | ACS Catal |
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| Main Authors: | , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
American Chemical Society
2017
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| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5724529/ https://ncbi.nlm.nih.gov/pubmed/29250456 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b00688 |
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