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Structural evidence for the covalent modification of FabH by 4,5-dichloro-1,2-dithiol-3-one (HR45)

We use mass spectrometry analysis and molecular modelling to show the established antimicrobial inhibitor 4,5-dichloro-1,2-dithiol-3-one (HR45) acts by forming a covalent adduct with the target β-ketoacyl-ACP synthase III (FabH). The 5-chloro substituent directs attack of the essential active site t...

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Detalhes bibliográficos
Publicado no:Org Biomol Chem
Main Authors: Ekström, Alexander G., Kelly, Van, Marles-Wright, Jon, Cockroft, Scott L., Campopiano, Dominic J.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5708339/
https://ncbi.nlm.nih.gov/pubmed/28715001
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7ob01396e
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