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Palladium-catalysed alkene chain-running isomerization()
We report a method for palladium-catalysed chain-running isomerization of terminal and internal alkenes. Using an air-stable 2,9-dimethyl-phenanthroline-palladium catalyst in combination with NaBAr(4) promoter, olefins are converted to the most stable double bond isomer at −30 to 20 °C. Silyl enol e...
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| Udgivet i: | Chem Commun (Camb) |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5705238/ https://ncbi.nlm.nih.gov/pubmed/28835962 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc04953f |
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