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Leaving Group Ability Observably Affects Transition State Structure in a Single Enzyme Active Site
A reaction’s transition state (TS) structure plays a critical role in determining reactivity and has important implications for the design of catalysts, drugs, and other applications. Here we explore TS structure in the enzyme alkaline phosphatase using hybrid Quantum Mechanics/Molecular Mechanics s...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5705186/ https://ncbi.nlm.nih.gov/pubmed/27186960 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03156 |
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