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Hydrolysis, polarity, and conformational impact of C-terminal partially fluorinated ethyl esters in peptide models

Fluorinated moieties are highly valuable to chemists due to the sensitive NMR detectability of the (19)F nucleus. Fluorination of molecular scaffolds can also selectively influence a molecule’s polarity, conformational preferences and chemical reactivity, properties that can be exploited for various...

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Bibliografske podrobnosti
izdano v:Beilstein J Org Chem
Main Authors: Kubyshkin, Vladimir, Budisa, Nediljko
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2017
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5704756/
https://ncbi.nlm.nih.gov/pubmed/29234471
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.241
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