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Hydrolysis, polarity, and conformational impact of C-terminal partially fluorinated ethyl esters in peptide models

Fluorinated moieties are highly valuable to chemists due to the sensitive NMR detectability of the (19)F nucleus. Fluorination of molecular scaffolds can also selectively influence a molecule’s polarity, conformational preferences and chemical reactivity, properties that can be exploited for various...

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Podrobná bibliografie
Vydáno v:Beilstein J Org Chem
Hlavní autoři: Kubyshkin, Vladimir, Budisa, Nediljko
Médium: Artigo
Jazyk:Inglês
Vydáno: Beilstein-Institut 2017
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5704756/
https://ncbi.nlm.nih.gov/pubmed/29234471
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.241
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