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Hydrolysis, polarity, and conformational impact of C-terminal partially fluorinated ethyl esters in peptide models

Fluorinated moieties are highly valuable to chemists due to the sensitive NMR detectability of the (19)F nucleus. Fluorination of molecular scaffolds can also selectively influence a molecule’s polarity, conformational preferences and chemical reactivity, properties that can be exploited for various...

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Bibliografische gegevens
Gepubliceerd in:Beilstein J Org Chem
Hoofdauteurs: Kubyshkin, Vladimir, Budisa, Nediljko
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Beilstein-Institut 2017
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5704756/
https://ncbi.nlm.nih.gov/pubmed/29234471
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.241
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